Effect of Ni doped BaTiO3 on the dielectric properties in the Ba(Ni1/3Nb2/3)xTi1-xO3 solid solution
Identifieur interne : 000150 ( France/Analysis ); précédent : 000149; suivant : 000151Effect of Ni doped BaTiO3 on the dielectric properties in the Ba(Ni1/3Nb2/3)xTi1-xO3 solid solution
Auteurs : Faiza. Boujelben [Tunisie] ; F. Bahri [Tunisie] ; C. Boudaya [Tunisie] ; A. Maalej [Tunisie] ; H. Khemakhem [Tunisie] ; A. Simon [France] ; M. Maglione [France]Source :
- Journal of alloys and compounds [ 0925-8388 ] ; 2009.
Descripteurs français
- Pascal (Inist)
- Wicri :
- topic : Composé minéral.
English descriptors
- KwdEn :
Abstract
New ferroelectric ceramics of AB03 perovskite type were synthesized in the Ba(Ni1/3Nb2/3)xTi1-xO3 (0 ≤ x ≤ 0.2) system by solid state reaction technique. The effect of the replacement of titanium by nickel and niobium in the B site on structural and dielectric properties was investigated. For this, we have use X-ray diffraction and dielectric characterizations. Samples in cubic phase were generally obtained with a sintering temperature of 1350 °C. Dielectric measurements revealed that the very small change in composition by the substitution of titanium by nickel and niobium in the BaTiO3 has a strong influence on the dielectric proprieties: fast decreasing of Tc or Tm (for BaTiO3 Tc = 340 K, for x=0.06, Tc =270 K and for x= 0.16, Tm = 150 K). The evolution from classic ferroelectric behavior for (0 ≤ x < 0.1) to relaxor behavior for (0.1 ≤ x ≤ 0.2) is emphasized.
Affiliations:
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Pascal:09-0472142Le document en format XML
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on the dielectric properties in the Ba(Ni<sub>1/3</sub>
Nb<sub>2/3</sub>
)<sub>x</sub>
Ti<sub>1-x</sub>
O<sub>3</sub>
solid solution</title>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Effect of Ni doped BaTiO<sub>3</sub>
on the dielectric properties in the Ba(Ni<sub>1/3</sub>
Nb<sub>2/3</sub>
)<sub>x</sub>
Ti<sub>1-x</sub>
O<sub>3</sub>
solid solution</title>
<author><name sortKey="Boujelben, Faiza" sort="Boujelben, Faiza" uniqKey="Boujelben F" first="Faiza." last="Boujelben">Faiza. Boujelben</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Laboratoire des Matériaux Ferroélectriques, Faculté des Sciences de Sfax, Route Soukra Km 3,5, B.P. 1171</s1>
<s2>3018 Sfax</s2>
<s3>TUN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>Tunisie</country>
<wicri:noRegion>3018 Sfax</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Bahri, F" sort="Bahri, F" uniqKey="Bahri F" first="F." last="Bahri">F. Bahri</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Laboratoire des Matériaux Ferroélectriques, Faculté des Sciences de Sfax, Route Soukra Km 3,5, B.P. 1171</s1>
<s2>3018 Sfax</s2>
<s3>TUN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
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<wicri:noRegion>3018 Sfax</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Boudaya, C" sort="Boudaya, C" uniqKey="Boudaya C" first="C." last="Boudaya">C. Boudaya</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Laboratoire des Matériaux Ferroélectriques, Faculté des Sciences de Sfax, Route Soukra Km 3,5, B.P. 1171</s1>
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<author><name sortKey="Maalej, A" sort="Maalej, A" uniqKey="Maalej A" first="A." last="Maalej">A. Maalej</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Laboratoire des Matériaux Ferroélectriques, Faculté des Sciences de Sfax, Route Soukra Km 3,5, B.P. 1171</s1>
<s2>3018 Sfax</s2>
<s3>TUN</s3>
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</affiliation>
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<author><name sortKey="Khemakhem, H" sort="Khemakhem, H" uniqKey="Khemakhem H" first="H." last="Khemakhem">H. Khemakhem</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Laboratoire des Matériaux Ferroélectriques, Faculté des Sciences de Sfax, Route Soukra Km 3,5, B.P. 1171</s1>
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</inist:fA14>
<country>Tunisie</country>
<wicri:noRegion>3018 Sfax</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Simon, A" sort="Simon, A" uniqKey="Simon A" first="A." last="Simon">A. Simon</name>
<affiliation wicri:level="3"><inist:fA14 i1="02"><s1>CNRS, Université Bordeaux, ICMCB, 87, avenue du Docteur A. Schweitzer</s1>
<s2>33608 Pessac</s2>
<s3>FRA</s3>
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</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Nouvelle-Aquitaine</region>
<region type="old region" nuts="2">Aquitaine</region>
<settlement type="city">Pessac</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Maglione, M" sort="Maglione, M" uniqKey="Maglione M" first="M." last="Maglione">M. Maglione</name>
<affiliation wicri:level="3"><inist:fA14 i1="02"><s1>CNRS, Université Bordeaux, ICMCB, 87, avenue du Docteur A. Schweitzer</s1>
<s2>33608 Pessac</s2>
<s3>FRA</s3>
<sZ>6 aut.</sZ>
<sZ>7 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Nouvelle-Aquitaine</region>
<region type="old region" nuts="2">Aquitaine</region>
<settlement type="city">Pessac</settlement>
</placeName>
</affiliation>
</author>
</analytic>
<series><title level="j" type="main">Journal of alloys and compounds</title>
<title level="j" type="abbreviated">J. alloys compd.</title>
<idno type="ISSN">0925-8388</idno>
<imprint><date when="2009">2009</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
<seriesStmt><title level="j" type="main">Journal of alloys and compounds</title>
<title level="j" type="abbreviated">J. alloys compd.</title>
<idno type="ISSN">0925-8388</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Cubic lattices</term>
<term>Dielectric properties</term>
<term>Ferroelectricity</term>
<term>Inorganic compounds</term>
<term>Niobates</term>
<term>Permittivity</term>
<term>Perovskites</term>
<term>Relaxor</term>
<term>Sintering</term>
<term>Solid solutions</term>
<term>Solid state reaction</term>
<term>Titanates</term>
<term>Transition element compounds</term>
<term>XRD</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Ferroélectricité</term>
<term>Propriété diélectrique</term>
<term>Réaction état solide</term>
<term>Diffraction RX</term>
<term>Frittage</term>
<term>Constante diélectrique</term>
<term>Réseau cubique</term>
<term>Relaxeur</term>
<term>Niobate</term>
<term>Titanate</term>
<term>Solution solide</term>
<term>Perovskites</term>
<term>Composé minéral</term>
<term>Composé de métal de transition</term>
<term>Transition ferroélectrique paraélectrique</term>
</keywords>
<keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Composé minéral</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">New ferroelectric ceramics of AB0<sub>3</sub>
perovskite type were synthesized in the Ba(Ni<sub>1/3</sub>
Nb<sub>2/3</sub>
)<sub>x</sub>
Ti<sub>1-x</sub>
O<sub>3</sub>
(0 ≤ x ≤ 0.2) system by solid state reaction technique. The effect of the replacement of titanium by nickel and niobium in the B site on structural and dielectric properties was investigated. For this, we have use X-ray diffraction and dielectric characterizations. Samples in cubic phase were generally obtained with a sintering temperature of 1350 <sub>°</sub>
C. Dielectric measurements revealed that the very small change in composition by the substitution of titanium by nickel and niobium in the BaTiO<sub>3</sub>
has a strong influence on the dielectric proprieties: fast decreasing of <sub>T</sub>
c or T<sub>m</sub>
(for BaTiO<sub>3</sub>
T<sub>c</sub>
= 340 K, for x=0.06, Tc<sub> </sub>
=270 K and for x= 0.16, T<sub>m</sub>
= 150 K). The evolution from classic ferroelectric behavior for (0 ≤ x < 0.1) to relaxor behavior for (0.1 ≤ x ≤ 0.2) is emphasized.</div>
</front>
</TEI>
<affiliations><list><country><li>France</li>
<li>Tunisie</li>
</country>
<region><li>Aquitaine</li>
<li>Nouvelle-Aquitaine</li>
</region>
<settlement><li>Pessac</li>
</settlement>
</list>
<tree><country name="Tunisie"><noRegion><name sortKey="Boujelben, Faiza" sort="Boujelben, Faiza" uniqKey="Boujelben F" first="Faiza." last="Boujelben">Faiza. Boujelben</name>
</noRegion>
<name sortKey="Bahri, F" sort="Bahri, F" uniqKey="Bahri F" first="F." last="Bahri">F. Bahri</name>
<name sortKey="Boudaya, C" sort="Boudaya, C" uniqKey="Boudaya C" first="C." last="Boudaya">C. Boudaya</name>
<name sortKey="Khemakhem, H" sort="Khemakhem, H" uniqKey="Khemakhem H" first="H." last="Khemakhem">H. Khemakhem</name>
<name sortKey="Maalej, A" sort="Maalej, A" uniqKey="Maalej A" first="A." last="Maalej">A. Maalej</name>
</country>
<country name="France"><region name="Nouvelle-Aquitaine"><name sortKey="Simon, A" sort="Simon, A" uniqKey="Simon A" first="A." last="Simon">A. Simon</name>
</region>
<name sortKey="Maglione, M" sort="Maglione, M" uniqKey="Maglione M" first="M." last="Maglione">M. Maglione</name>
</country>
</tree>
</affiliations>
</record>
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